...
By Train:
From Münster: Take a regional train (RB 64, Euregio-Bahn) to Enschede. The journey is about 1.5 hours. https://www.deutschebahn.com/de
From Dortmund: Travel via Münster to connect to the RB 64, with a total journey time of about 2.5 hours.
By Car:
From Münster: Take the A1 and B54 motorways, driving 80 km (50 miles) in about 1 hour.
From Dortmund: Use the A1 and A31 motorways, driving about 130 km (80 miles) in 1.5 hours.
...